Mark '--with-isa-spec' option out of date.

[pz9115]

Currently, the '--with-isa-spec' is planning to replace with '--with-profiles', mark it out of date at first.

[cmuellner]

In riscv_subset_list::to_string, I can still see that riscv_isa_spec has an effect in GCC (zifencei and zicsr).
Also, TARGET_DEFAULT_ISA_SPEC is still set in gcc/config.gcc.
Further, upstream GCC does not mark this flag as deprecated or out-of-date.
We may follow upstream GCC if they do so, but we should not deprecate a feature here that is fully supported in GCC (even if it is rarely used these days).